Reliance Jio Customer Care Numbers | Jiocare Customer Service Reliance Jio Head Office Address: Company Secretary and Compliance Officer, Reliance Jio Infocomm Ltd, 9th Floor, Maker Chambers IV, 222, Nariman Point, Mumbai – 400 021, Maharashtra, India Website Address is https://www.jio.com/ Reliance Jio India Customer Care Toll free numbers:  Toll free Complaint & Service Number: 199 from jio Call JioCare experts 24X7,